Breakpoint Chlorination Dose

The combined chlorine in the water, and the shock dose that burns it off.

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Example

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Checked against published worked examples from: Indiana Department of Health.

Details, formula, and sources

ScopeCombined chlorine (chloramines) = total - free, and the breakpoint shock dose = ratio x combined (commonly 10:1). Total 1.5, free 1.0 -> 0.5 ppm combined, a 5 ppm shock; shock past breakpoint (a partial dose worsens it). The label and testing govern.

Formula or tablecombined = total - free; dose_ppm = ratio x combined (ratio ~10); optional lb_product = dose_ppm x (gal/1e6) x 8.34 / (avail/100).

Source and editionThe breakpoint (superchlorination) chlorination rule and Standard Methods 4500-Cl, by name.

Free accessThe breakpoint-curve behavior and the ~10:1 shock rule are published free by pool-care and water-treatment references (Standard Methods 4500-Cl). The product label and testing govern.

What governsEstimate. AHJ and licensed professional govern.

API field namestotal_ppm, free_ppm, ratio, gallons, avail, combined_ppm, dose_ppm

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